Abstract
The desire to obtain a higher share for silica in tire compounding has been one motivation in the development of silane coupling agents. This development has reached a stage where at least a partial replacement of semi‐active and active carbon blacks with silane‐modified white fillers is technically feasible although costs are still too high. Nevertheless, silica tires with bis‐(3‐triethoxisilylpropyl)‐tetrasulfide (TESPT) have been built on a development scale and tested under various conditions.
Over the last ten years, the coupling agent TESPT has developed into a special rubber chemical. This is due to its simultaneous capability of forming equilibrium cure systems, polysulfidic crosslinks with extremely high thermal stability, and rubber‐to‐filler bonds to improve silica‐rubber interaction. In conjunction with silica, TESPT gives superior physical vulcanizate properties such as low heat build‐up, better performance under continuous deformation, and better tear and cutting resistance than vulcanizates with carbon black only. Its present main application is in truck, off‐the‐road, and earth‐mover tires to solve specific tire problems.