Abstract
Tire manufacturers exploit the use of cure kinetics models in the FEA for setting optimum cure cycles. The following cure process assures production of superior tire compound properties in a cost competitive manner.
It is well known that overcure of many tire compounds results in reversion. This effect is directly observed as a decrease in modulus relative to the optimum value. Reversion is directly observed on rheometric isothermal torque‐time profiles which pass through a maximum torque value. Reversion usually implies a deleterious effect on vulcanizate properties.
We are not aware of any cure models, given in the literature, which adequately account for reversion. Such models cannot be used to accurately optimize cure cycles in those cases where the extent of reversion is significant.
This paper presents a cure kinetics model that accounts for reversion. Also, the model does not need to use an “induction time.” Rather, the model predicts a continuous torque‐time trace, initially rising slowly but eventually rising sharply. The predicted and observed torque‐time traces, as shown in this paper, exhibit excellent agreement over the entire rheometric time scale. Furthermore, the constants of the model can be interpreted as indicators of the basic mechanism of the curing process, i.e., rate constants for creation and loss rates of different types of cross‐links, therefore enabling a prediction of the extent of reversion during a cure cycle.